Always a favorite of mine, Gordon Lightfoot did so many good things. But with Ian and Sylvia as a bonus, this one is hard to beat. Thanks for finding it.
Aaron Lewis lead singer from Staind (Springfield MA), ventured over into country after Staind. His voice can do about any genre.
Country Boy
Here is one from Mary Black that has a special meaning for me as both of my grandfathers worked mines in the Appalachians for a bit. One in coal, and one in fire clay which was the material used make the bricks to line the blast furnaces of Pittsburgh.
Toby Keith
What do you get when you cross Lil Nas X with Miley's daddy? Either Country Rap or Southern Hip-Hop.
(and yes it does sample NIN's 34 Ghosts IV)
Old Town Road