I'd say that some of the B12 schools are theoretically better options (i.e. have better football programs and markets--Texas, OU, Mizzou), but they either aren't likely to go due to money (Texas/OU) or geographic (Texas/OU/Mizzou) reasons.
The word is that Mizzou has an offer right now from the B12. That's what I'm basing my comments on. If they have rejected the SEC, they aren't going to the ACC. I they aren't going, none of the others are (barring B12's collapse--which is still possible). Once none of the B12 schools aren't going to the ACC, you don't really have a better option Athletically, Geographically, or Academically than UConn.
Also, thank you for responding to the points more clearly.