Va Tech was lucky to get to the ACC thanks to the lobbying of the Virginia State Legislature. Otherwise they would have been in the AAC with UConn.
They'd've gotten the Louisville spot or gone with Pitt, if the BC block of UConn still worked. (UConn was in a stronger place in Round 2 only 9 months removed from the Fiesta Bowl, so it may not have, given the valuation for Syracuse - UConn was preferred, Syracuse - Pitt good enough)
Round 1 (2004): Miami, BC, Syracuse (Virginia Tech IRL)
Round 2 (2011): Pitt, UConn
Round 3 (Maryland backfill): Virginia Tech (football school selection)