Why couldn't she take those shots with no hesitation at UConn instead of freezing?
Part of it is floor spacing. First, this is 3x3, so less chance for help side defenders/double teams. Also, in the W in general, players can/will shoot from anywhere so there’s less chance of a player sagging off their assignment to double (if they do, it can make for an easy kick out to whoever is open and the defense could pay for that). Zone defense is also almost nonexistent (if not entirely nonexistent) because of the defensive 3 second rule and players being able to take/make 3s more regularly than at the college level.
Edit: Basically I’m saying ONO has more room to operate, which makes her life easier. Also, everyone has to be a scoring threat in the W, so her taking shots is a necessity if she has a shot open rather than her being a 3rd, 4th, or 5th option for a play.