If she said UConn has an RPI in the 30's, then she was even more clueless than usual. Current UConn RPI is #7.
One big difference between RPI and models like Massey is, as others have pointed out, that the RPI only looks at whether you win or lose - not the margin of victory. In the RPI, a one-point win is the same as an 80-point win. Further, the RPI evaluates the strength of the teams you beat solely by their records, not by who they beat or lost to and by how much. Also a team gets less credit for its own wins than it does for the wins of its opponents. If a team had a W-L percentage of 0.0% (i.e. no wins for the entire season), played opponents with a W-L percentage of 75%, who in turn played opponents with a W-L percentage of 60%, its RPI (ignoring home/road factor) would be 52.5% - well above average.
In theory a team could have a record of 0-30 and lose every game by 50+ points, and end up ranked in the top 5 in the nation in RPI. It's not going to happen - but it could, if a team was able to put together a schedule that only included road games vs the seven or eight power-conference teams with the best W-L percentages.