Not with the Longhorn network and when Texas will not engage in revenue sharing...
I don't think you have a very good handle on the situation.
The LHN is the very business model a school like Florida State wants to follow, not some silly socialist system where everyone gets to suckle the teat of the programs whose brands are worth something (who, BTW, are driving the lucrative Tier 1 and 2 deals that are shared equally, even if you're basically worth nothing from a brand perspective like Iowa State). As is, ESPN owns the entire ACC's Tier 3 rights for football, and that's included in the $17 million/year/school. In the Big XII, FSU would receive more than $17 million/year for Tier 1 and 2 rights alone AND easily strike an independent deal with ESPN or another network for its Tier 3 rights.
The big football schools of the ACC are not totally happy (and their fans really aren't), and if they a) don't have an in-state partner tying them down (see: Va Tech), and b) they are in an SEC state where the resident SEC school will block admission to the ACC until the end of time (see: Clemson and Florida State), they are going to consider the Big XII.
In order of likelihood, the Big XII is targeting the following schools:
1. Lousiville
2. Clemson
3. Florida State
4. Notre Dame