The ACC is the best fit. Better than the Big 10 by a mile. The Big 10 is a classy conference, but more of our alums are on the Atlantic seaboard than the midwest. If they added Rutgers and UConn to the conference then really the only conference opponent that we would be without that we actually gave a crap about is WVU, (although I would kind of miss Cincy).
I would rather travel to Charlottesville in the fall than Bloomington. When people think of joining the Big 10, they think of Michigan, Ohio State or even Wisconsin. But they also forget about dogs like Illinois, Michigan State, Indiana and let's face it, nobody is going to get in a car and road trip it to Madison, Iowa City, and Minneapolis.
In the ACC, BCU, SU, Pitt, RU (potentially), Maryland, UVA and VT are all within a 9-10 hour drive. Well, VT is probably a little beyond 10 hrs..